A series of Early English Books Online searches turns up the following earliest occurrences of the forms "different fro," "different from," "different than," "different then," and "different to."
From Thus Endeth the Prologue of This Book Named. Cordʻyal. (1479):
O how sore shal our lorde venge hym then̄ vppon the dampned synners As it is saide in Ec[c]lesiastico in the vij chapitre. The flesshe of synners shal haue vengeance by fire. This fire of the gehenne of helle is different from the materiall fire principally in ◊ thinges. First in fyersnesse & egernesse fo[r] ye power of it in brenning is infenite. wherfor seith seint Sebastian̄. When̄ the angel of heuen rowned hym in the ere. he seyde that our sensible fire is no more like the fire of hell then the fire peynted vpon a wall is like our materiale fire. Secundly in enduring.
From a 1506 printing of Jacobus de Gruytrode, The Mirroure of Golde for the Synfull Soule:
Oure iniquities hath put deuision bitwene god & vs / And our synnes hath withdrawen his face frome vs / that is to say frome our vision. For there is noon in paradise so iuste nor so holy? if he cōmytted synne? but a noon he shulde fall in to he. and lese the loue of god / to the whiche purpose saithe saint Augustyne / he that cōmytteth faulte or synne agaynst his true and moste true frende? ought to be reputed greatly reprouable Nowe then it behoueth the to knowe and vnderstond that by a more stronge reason he that cōmyteth faulte or synne against the souerayn & debonayre all mighty god? ought well to be reputed and of al holden abhomynable. Four thely it is to knowe that by synne the synner is Iuged to the Iebet of hell / & for so moche as the lawe of god is not farre different fro the lawe of man? Therfore in lyke maner al the brekers of the lawe of man? whiche dothe trespace againste the kingis Royall magestie? be worthy to deth / and ought to be punysshed corporally.
From The Shepardes Kalender (1570[?]):
And thus the day hath xii. houres, and the nyght xii. also the whych be temporal houres, different to the houres of the clockes, the which be artificials. Shepardes sayd that Saturne and Mars be euyll planettes. Iupiter and Uenus good, Sol and Luna halfe good and halfe euyll. The parey toward a good planet is good and the party towarde the euyl planet is nought. Mercury conioyned with a good planette is good, and with an euyll planet he is nought and they vnderstande this as to [t]he inflicences good or euyll that bin of the sayde planetes there folowynge.
The houres of the planets ben different to them of clockes, for the houres of clockes ben egall at all tymes eche of .lx. minutes, but they of the planets whē the dayes and the nightes be egall that the sonne is in one of the equinocces they be egal, but as sone as the dayes lengtheneth or shortneth, so dothe the natural houres, by this it is conuenient alway for the day to haue .•ii tēporal houres, & the nyght also, and when the dayes be long, & the houres longe, and when the dayes ben short and the houres short, in lykewise is the night, and neuerthelesse an houre of the day, and an houre of the night together haue vi. score minutes, as many as two houres artyficialles, for that the one leueth the other taketh.
From a 1594 translation of Louis Leroy, Of the Interchangeable Course, or Variety of Things in the Whole World and the Concurrence of Armes and Learning, Thorough the First and Famousest Nations: From the Beginning of Ciuility, and Memory of Man, to This Present:
The other Hetrurian letters which are seen yet at this day in the ancient sepulchers, are altogether vnknowen: Others searching the same yet more deeply, and fetching it farther off, affime that they were first inuented by the Ethiopians, who deliuered them to the Egiptians; the Egiptians to the Assyrians; the Assyrians to the Phenicians; the Phenicians to the Pelagians; the Pelagians to the Latins; the Latins to the Italians, Frenchmen, Spaniards, Almains, Englishmen, Scots, Noruegians, Suecians, Polacques, and Hungarians.
The Characters of the letters are no lesse different then the tongues; & can not serue any tongue but that wherunto they were ordayned; nor represent the entier, & natural pronunciation, no, not of their owne; which changeth not onely from towne to towne, but almost from village to village; for Greek could not be written in Latin letters, nor the Latin in Greek letters: and the Greeks and Latins do not alwaies pronounce as they write; but to make the sound of their words softer, do change the pronounciation of some letters, ta∣king thone for thother: whereof ther is a complaint made in Lucian to the iudgment of the vowels.
From a 1603 translation (by Philemon Holland) of Plutarch, The Philosophie, Commonlie Called, the Morals Written by the Learned Philosopher Plutarch of Chæronea:
To the Antigenidians likewise they might impute ignorance of the Dirionian Musicke, for the same cause, as also the minstrels & harpers, as ignorant of the maner of Timotheus his Musicke. For they have in maner all betaken themselves to patcheries and fallen to the Poëmes of Polydius. On the other side, if a man consider aright, and with experience make comparison betweene that which then was and that which now is, he shall finde that variety and diversity was in use and request even in those daies also. For the ancient Musicians used in their numbers and measure, their variety, much more diverse & different than now it is. So that we may boldly say that the varietie of thymes, the difference also and diversitie of strokes was then more variable. For men in these daies love skill and knowledge, but in former times they affected numbers and measures. So that it appeareth plainely that the ancients abstained from broken Musicke and song, not because they had no skill, but for that they had no will to approve thereof.
To summarize, the EEBO database yields the following early occurrences of the various forms that I searched for:
- 1479 different from
- 1507 different fro
- 1570(?) different to
- 1594 different then
- 1603 different than
Evidently, all five forms have appeared in published works in English for at least 400 years.
Also of possible interest is the number of matches for each of the five forms in the EEBO database, which runs from 1475 through 1700:
- different from: 6,434 matches
- different fro: 78 matches
- different to: 325 matches (many of them not functioning as a comparative phrase)
- different then: 91 matches (some of them not involving then in the sense of "than")
- different than: 60 matches
Clearly "different from" was the dominant form during this period, although the others did occasionally appear.