If you were speaking that sentence, you'd say
How to install an ess ess ell certificate.
The word that describes the letter S - which I represent as "ess" above - begins with a vowel sound, so "an" is appropriate.
If it's an abbreviation that's typically pronounced as a word, instead of spelling out the letters, then normal rules apply:
They're having a NATO exercise
People pronounce NATO as "nato", not as "enn ay tee oh."
Some abbreviations are treated differently by different people. The term for a web address is "URL." I think most people spell out the letters, making it "a URL" (a you are ell), but some prefer to speak it as a word - "an URL" (an earl).
Isn't English fun?