There is no "grammatically correct" way of appending OP's question tag "won't they [be]?" to the statement, because the operative verb in the preceding main clause is hope, not will be sent. Thus...
"You hope it is, don't you?" is a valid utterance (don't echoes you do hope), but
"You hope it is, isn't it?" isn't valid English (it would have to be "It is, isn't it?").
EDIT: A tag question can occur in a wide variety of contexts, but checking related earlier questions I see mention of only the most basic usage (convert a statement into a genuine question).
Tag questions are primarily a feature of "interactive speech", rather than writing, but in practice they're not normally "questions" expecting "answers". They're usually a rhetorical device implicitly assuming an affirmative answer, serving to emphasise the truth of the original statement. And very often even that preceding statement only indirectly addresses the real subject...
"Darling, you do love me, don't you?" (could meaningfully be answered with the expected "Yes").
"I married you, didn't I?" (doesn't directly answer the question, nor does it expect any answer as such).
In the above case, the emphasis is probably intended to amplify reassurance, but the form is also commonly used to indicate/amplify belligerence...
"I'm sorry I spilled your pint"
"You're cruising for a bruising, aren't you?" (more likely "ain't you?" in my neck of the woods!).
In OP's example, it simply isn't appropriate to append the grammatically valid tag question, since...
"I hope all the scheduled payments will be sent tonight, don't I?"
...could only reasonably be interpreted as a belligerent response to a question such as "Do you even care whether our suppliers will make deliveries as normal next week?"